Grease your 6-quart slow cooker insert with butter or nonstick cooking spray to prevent sticking.
Cut the brioche bread into 1-inch cubes and layer them in the slow cooker along with chopped pecans if using.
In a large bowl, whisk together 8 eggs, 3 cups milk, 1/2 cup maple syrup, 1 tablespoon vanilla extract, 1 teaspoon salt, 2 teaspoons cinnamon, and 1/2 teaspoon nutmeg until well combined.
Pour the egg custard mixture over the bread cubes in the slow cooker. Gently stir to coat all the bread pieces. Let sit for 30 minutes if possible, or refrigerate overnight for best results.
In a small bowl, mix 1/2 cup brown sugar and 1 teaspoon cinnamon. Sprinkle this mixture evenly over the soaked bread. Dot the top with butter pieces.
Cover with the lid and cook on HIGH for 2 to 2.5 hours or LOW for 3 to 4 hours, until the center is set and edges are golden brown.
Serve warm with maple syrup, powdered sugar, fresh berries, or whipped cream. Use the warm setting to keep it ready for serving.